Research on synthesis of imidazole-based ionic liquids as metal corrosion inhibitors

158 views

Authors

  • Ha Quoc Bang (Corresponding Author) Institute of Chemistry and Materials, Academy of Military Science and Technology
  • Nguyen Huu Van Institute of Chemistry and Materials, Academy of Military Science and Technology
  • Nguyen Duy Anh Institute of Chemistry and Materials, Academy of Military Science and Technology

DOI:

https://doi.org/10.54939/1859-1043.j.mst.94.2024.102-108

Keywords:

Ionic liquids; Corrosion inhibitor; Imidazole; 1-hexadecylbromide.

Abstract

Ionic liquids (ILs) have gained significant attention in recent years as potential corrosion inhibitors to various applications. Traditional corrosion inhibitors, such as organic compounds and inorganic salts, have limitations in terms of toxicity, volatility, and environmental impact. However, ionic liquids offer a promising alternative. Ionic liquids are salts that exist in a liquid state at or below 100 degrees Celsius. They typically comprise an organic cation and an inorganic or organic anion. The unique combination of a liquid state and ionic nature gives them several advantageous properties, such as high thermal stability, low vapor pressure, and tunable physicochemical properties. Additionally, the charged nature of the ionic liquid allows for electrochemical interactions with the metal surface, further enhancing corrosion inhibition. In this paper, imidazole-based ionic liquids were synthesized by alkylation of imidazole derivatives using 1-bromohexadecane. The anti-corrosion properties of the material were evaluated using the weight method and potentiodynamic polarization method. Results showed that the synthesized ILs are good corrosion inhibitor for CT3 steel.

References

[1]. Kobzar YL, Fatyeyeva K. “Ionic liquids as green and sustainable steel corrosion inhibitors: recent developments”, Chem Eng J., Vol. 425, 131480, (2021). DOI: https://doi.org/10.1016/j.cej.2021.131480

[2]. Nkuna AA, Akpan ED, Obot IB, Verma C, Ebenso EE, Murulan LC., “Impact of selected ionic liquids on corrosion protection of mild steel in acidic medium: experimental and computational studies”. J Mol Liq, Vol. 314, 113609, (2020). DOI: https://doi.org/10.1016/j.molliq.2020.113609

[3]. Kowsari E, Arman SY, Shahini MH, Zandi H, Ehsani A, Naderi R., “In situ synthesis, electrochemical and quantum chemical analysis of an amino acid derived ionic liquid inhibitor for corrosion protection of mild steel in 1M HCl solution”, Corrosion Sci, Vol. 112, pp. 73-85, (2016). DOI: https://doi.org/10.1016/j.corsci.2016.07.015

[4]. Swathi NP, Samshuddin S, Aljohani TA, Rasheeda K, Alva VDPA, Alomari FY., “A new 1,2,4-triazole derivative as an excellent corrosion inhibitor: electrochemical experiments with theoretical validation”. Mater Chem Phys, Vol. 291, 126677, (2022). DOI: https://doi.org/10.1016/j.matchemphys.2022.126677

[5]. Cui M, Ren S, Zhao H, Wang L, Xue Q., “Novel nitrogen doped carbon dots for corrosion inhibition of carbon steel in 1 M HCl solution”. Appl Surf Sci, Vol. 443, pp. 145-156, (2018). DOI: https://doi.org/10.1016/j.apsusc.2018.02.255

[6]. Ahmed SA, Awad MI, Althagafi II, Altass HM, Morad M, Alharbi A., “Newly synthesized indolium based ionic liquids as unprecedented inhibitors for the corrosion of mild steel in acid medium”. J Mol Liq. Vol. 291, 111356, (2019). DOI: https://doi.org/10.1016/j.molliq.2019.111356

[7]. Pang L, Wang ZB, Lu MH, Lu Y, Liu X, Zheng YG, “Inhibition performance of benzimidazole derivatives with different heteroatoms on the under-deposit corrosion of carbon steel in CO2 -saturated solution”. Corrosion Sci, Vol. 192, 109841, (2021). DOI: https://doi.org/10.1016/j.corsci.2021.109841

[8]. Kolle, P.; Dronskowski, R. “Synthesis, crystal structures and electrical conductivities of the ionic liquid compounds butyl dimethylimidazolium tetrafluoroborate, hexafluoroborate and hexafluoroantimonate”. Eur. J. Inorg. Chem, Vol. 11, pp. 2313-2320, (2009). DOI: https://doi.org/10.1002/ejic.200300940

[9]. Earle, M. J.; Esperanc, J. M. S. S.; Gilea, M. A.; Lopes, J. N. C.; Rebelo, L. P. N.; Magee, J. W.; Seddon, K. R.; Widegren, J. A. “The distillation and volatility of ionic liquids”, Nature, Vol. 72, pp. 1391-1398, (2006).

[10]. Eapen T., Deepthi T., S. Bhuvaneswari, K.P. Vijayalakshmi, Benny K. George, “1-hexadecyl-3-methylimidazolium chloride: Structure, thermal stability and decomposition mechanism”, Journal of Molecular Liquids, Vol. 249, pp. 404-411, (2018). DOI: https://doi.org/10.1016/j.molliq.2017.11.029

Downloads

Published

22-04-2024

How to Cite

Ha Quoc, B., V. Nguyen Huu, and D. A. Nguyen. “Research on Synthesis of Imidazole-Based Ionic Liquids As Metal Corrosion Inhibitors”. Journal of Military Science and Technology, vol. 94, no. 94, Apr. 2024, pp. 102-8, doi:10.54939/1859-1043.j.mst.94.2024.102-108.

Issue

Section

Chemistry, Biology & Environment

Most read articles by the same author(s)