Study on the synthesis of nano ZnO/porphyrin, used to methylene blue

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Authors

DOI:

https://doi.org/10.54939/1859-1043.j.mst.80.2022.114-119

Keywords:

Nano ZnO; Porphyrin; Self-assembly; Oxidation; Organic dye.

Abstract

The study has successfully synthesized porphyrin-based hybrid nanomaterials by using the meso-tetra(4-carboxylphenyl) porphyrin self-assembly hybrid with ZnO nanoparticles. The properties of the composites were demonstrated by scanning electron microscopy and X-ray diffraction (XRD) spectroscopy. The photocatalytic properties of the resulting hybrid nanomaterials were investigated in the treatment of methylene blue under visible light activation. The methylene blue degradation efficiency reached 97% with MB initial concentration at 10 ppm and 0.4 mg photocatalyst after 3 hours of treatment.

References

[1]. Adnan, M. A. M.; Julkapli, N. M.; Abd Hamid, S. B. “Review on ZnO hybrid photocatalyst: impact on photocatalytic activities of water pollutant degradation”. Rev. Inorg. Chem., 36, pp. 77−104, (2016).

[2]. Sun, W.-j.; Li, J.; Mele, G.; Zhang, Z.-q.; Zhang, F.-x. “Enhanced photocatalytic degradation of rhodamine B by surface modification of ZnO with copper (II) porphyrin under both UV−vis and visible light irradiation”. J. Mol. Catal. A: Chem., 366, pp. 84−91, (2013).

[3]. La, D. D.; Nguyen-Tri, P.; Le, K. H.; Nguyen, P. T.; Nguyen, M. D.-B.; Vo, A. T.; Nguyen, M. T.; Chang, S. W.; Tran, L. D.; Chung, W. J. “Effects of antibacterial ZnO nanoparticles on the performance of a chitosan/gum arabic edible coating for post-harvest banana preservation”. Prog. Org. Coat., 151, No. 106057, (2021).

[4]. La, D. D.; Tran, C. V.; Hoang, N. T.; Ngoc, M. D. D.; Nguyen, T. P.; Vo, H. T.; Ho, P. H.; Nguyen, T. A.; Bhosale, S. V.; Nguyen, X. C.; et al. “Efficient photocatalysis of organic dyes under simulated sunlight irradiation by a novel magnetic CuFe2O4@ porphyrin nanofiber hybrid material fabricated via self-assembly”. Fuel, 281, No. 118655, (2020).

[5]. La, D. D.; Rananaware, A.; Thi, H. P. N.; Jones, L.; Bhosale, S. V. “Fabrication of a TiO2@ porphyrin nanofiber hybrid material: a highly efficient photocatalyst under simulated sunlight irradiation”. Adv. Nat. Sci.: Nanosci. Nanotechnol. 8, No. 015009, (2017).

[6]. La, D. D.; Nguyen, T. A.; Nguyen, X. S.; Truong, T. N.; Ninh, H. D.; Vo, H. T.; Bhosale, S. V.; Chang, S. W.; Rene, E. R.; Nguyen, T. H.; et al. “Self-assembly of porphyrin on the surface of a novel composite high performance photocatalyst for the degradation of organic dye from water: Characterization and performance evaluation”. J. Environ. Chem. Eng. 9, No. 106034, (2021).

[7]. La, D.; Hangarge, R.; V Bhosale, S.; Ninh, H.; Jones, L.; Bhosale, S. “Arginine-mediated self-assembly of porphyrin on graphene: a photocatalyst for degradation of dyes”. Appl. Sci. 7, 643, (2017).

[8]. La, D. D.; Bhosale, S. V.; Jones, L. A.; Bhosale, S. V. “Arginineinduced porphyrin-based self-assembled nanostructures for photocatalytic applications under simulated sunlight irradiation”. Photochem. Photobiol. Sci., 16, pp. 151−154, (2017).

[9]. Sandoval, A.; Hernández-Ventura, C.; Klimova, T. E. “Titanate nanotubes for removal of methylene blue dye by combined adsorption and photocatalysis”. Fuel, 198, pp. 22−30, (2017).

Published

28-06-2022

How to Cite

Vo, H. T. “Study on the Synthesis of Nano ZnO/Porphyrin, Used to Methylene Blue”. Journal of Military Science and Technology, no. 80, June 2022, pp. 114-9, doi:10.54939/1859-1043.j.mst.80.2022.114-119.

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Section

Research Articles