STRUCTURE, MORPHOLOGICAL, MAGNETIC AND OPTICAL PROPERTIES OF CuxMg1-xFe2O4 (x = 0, 0.5, 1) NANO FERRITES SYNTHESIZED BY CO-PRECIPITATION METHOD
149 viewsKeywords:
Spinel ferrites; Nanoparticles; Ferromagnetic materials; Superparamahnetic.Abstract
CuxMg1.xFe2O4 nanoparticles were successfully synthesized by co-precipitation. The samples were calcined at 900 oC for 3 h and X-ray diffraction analysis showed that Cu0.5Mg0.5Fe2O4 had a single phase cubic spinel structure, while formation of secondary phase of Fe2O3 was observed in XRD patterns of CuFe2O4, MgFe2O4. The saturation magnetization (Ms) of Cu0.5Mg0.5Fe2O4 is in between the saturation magnetization values of CuFe2O4 and MgFe2O4 nanoparticles, CuFe2O4 is a ferromagnetic material, while MgFe2O4 and Cu0.5Mg0.5Fe2O4 show superparamagnetic behavior. The synthesized spinel ferrites were fully characterized using scanning electron microscopy (SEM), FTIR spectroscopy, energy dispersive spectroscopy (EDS) and UV-vis spectrophotometry.
References
[1]. Maensiri, S., et al., “A simple route to synthesize nickel ferrite (NiFe2O4) nanoparticles using egg white,” Scripta materialia, Vol. 56(9), p. 797-800, (2007).
[2]. Reddy, A.E., et al., “Construction of novel nanocomposite ZnO@ CoFe2 O4 microspheres grown on nickel foam for high performance electrochemical supercapacitors,” Analytical Methods, Vol. 10(2), p. 223-229, (2018).
[3]. Popov, A.M., et al., “Determination of lithium in lithium-ionic conductors by laser-enhanced ionization spectrometry with laser ablation,” Journal of Analytical Atomic Spectrometry, Vol. 29(1), p. 176-184, (2014).
[4]. Céspedes, E., et al.,“Bacterially synthesized ferrite nanoparticles for magnetic hyperthermia applications,” Nanoscale, Vol. 6(21), p. 12958-12970, (2014).
[5]. Srinivasan, S.Y., et al., “Applications of cobalt ferrite nanoparticles in biomedical nanotechnology,” Nanomedicine, Vol. 13(10), p. 1221-1238, (2018).
[6]. Yoon, T.J., et al., “Multifunctional nanoparticles possessing a “magnetic motor effect” for drug or gene delivery,” Angewandte Chemie, Vol. 117(7), p. 1092-1095, (2005).
[7]. 7. Šutka, A. and K.A. Gross, “Spinel ferrite oxide semiconductor gas sensors,” Sensors Actuators B: Chemical, Vol. 222, p. 95-105, (2016).
[8]. Salman, G., A. Bohan, and G. Jaed, “Use of Nano-Magnetic Material for Removal of Heavy Metals from Wastewater,” Engineering Technology Journal, Vol. 35(9 Part (A) Engineering), p. 903-908, (2017).
[9]. Vamvakidis, K., et al., “Diverse Surface Chemistry of Cobalt Ferrite Nanoparticles to Optimize Copper (II) Removal from Aqueous Media,” Materials, Vol. 13(7), p. 1537, (2020).
[10]. Abraham, A.G., et al., “Enhanced magneto-optical and photo-catalytic properties of transition metal cobalt (Co2+ ions) doped spinel MgFe2O4 ferrite nanocomposites,” Journal of Magnetism Magnetic Materials, Vol. 452, p. 380-388, (2018).
[11]. Ortiz-Quiñonez, J.-L., U. Pal, and M.S. Villanueva, “Structural, magnetic, and catalytic evaluation of spinel Co, Ni, and Co–Ni ferrite nanoparticles fabricated by low-temperature solution combustion process,” ACS omega, Vol. 3(11), p. 14986-15001, (2018).
[12]. Lassoued, A., et al., “Synthesis and magnetic characterization of Spinel ferrites MFeO (M= Ni, Co, Zn and Cu) via chemical co-precipitation method,” Journal of Materials Science: Materials in Electronics, Vol. 28(24), (2017).
[13]. Bhandare, S.V., et al., “Mechanistic insights into the sol-gel synthesis of complex (quaternary) Co–Mn–Zn-spinel ferrites: An annealing dependent study,” Ceramics International, Vol. 46(11), p. 17400-17415, (2020).
[14]. Mohammad, A.M., S.M.A. Ridha, and T.H. Mubarak, “Dielectric properties of Cr-substituted cobalt ferrite nanoparticles synthesis by citrate-gel auto combustion method,” International Journal of Applied Engineering Research, Vol. 13(8), p. 6026-6035, (2018).
[15]. Bid, S. and S. Pradhan, “Preparation of zinc ferrite by high-energy ball-milling and microstructure characterization by Rietveld’s analysis,” Materials Chemistry Physics, Vol. 82(1), p. 27-37, (2003).
[16]. Nguyen, L.T., et al., “A Facile Synthesis, Characterization, and Photocatalytic Activity of Magnesium Ferrite Nanoparticles via the Solution Combustion Method,” Journal of Chemistry, Vol. 2019, (2019).
[17]. Kader, S.S., D.P. Paul, and S.M. Hoque, “Effect of temperature on the structural and magnetic properties of CuFe2O4 nano particle prepared by chemical co-precipitation method,” International Journal of Materials, Mechanics Manufacturing, Vol. 2(1), p. 5-8, (2014).
[18]. Anandan, S., et al., “Magnetic and catalytic properties of inverse spinel CuFe2O4 nanoparticles,” Journal of Magnetism and Magnetic Materials, Vol. 432, p. 437-443, (2017).
[19]. Shih, Y.-J., et al., “Synthesis of magnetically recoverable ferrite (MFe2O4, M Co, Ni and Fe)-supported TiO2 photocatalysts for decolorization of methylene blue,” Catalysis Communications, Vol.72, p. 127-132, (2015).
[20]. Zaki, H., S. Al-Heniti, and T. Elmosalami, “Structural, magnetic and dielectric studies of copper substituted nano-crystalline spinel magnesium zinc ferrite,” Journal of Alloys compounds, Vol. 633, p. 104-114, (2015).
[21]. Airimioaei, M., et al., “Synthesis and functional properties of the Ni1−xMnxFe2O4 ferrites,” Journal of alloys compounds, Vol. 509(31), p. 8065-8072, (2011).
[22]. Shannon, R.D., “Revised effective ionic radii and systematic studies of interatomic distances in halides and chalcogenides,” Acta crystallographica section A: crystal physics, diffraction, theoretical general crystallography, Vol. 32(5), p. 751-767, (1976).
[23]. Nguyen, T.B. and R.-a.J.R.A. Doong, “Heterostructured ZnFe2 O4/TiO2 nanocomposites with a highly recyclable visible-light-response for bisphenol A degradation,” RSC Adv, Vol. 7(79), p. 50006-50016 (2016).
[24]. Manimozhi, V., et al., “Preparation and characterization of ferrite nanoparticles for the treatment of industrial waste water,” Digest Journal of Nanomaterials and Biostructures, Vol. 11(3), p. 1017-1027, (2016).
[25]. Sezgin, N., et al., “Synthesis, characterization and, the heavy metal removal efficiency of MFe2O4 (M= Ni, Cu) nanoparticles,” Ekoloji, Vol. 22(89), p. 89-96, (2013).
[26]. Raju, M.K.J.C.S.T., “FT-IR studies of Cu substituted Ni-Zn ferrites for structural and vibrational investigations,” Chemical Science Transactions, Vol. 4(1), p. 137-142, (2015).
