Electrochemistry: From theory to technology and application (Part 2)

179 views

Authors

  • Nguyen Duc Hung (Corresponding Author) Institute of Environmental Technology, Vietnam Academy of Science and Technology

DOI:

https://doi.org/10.54939/1859-1043.j.mst.78.2022.3-19

Keywords:

Electrolyte; Electrode potention; Current density; Anodic process; Cathodic process.

Abstract

Electrochemistry is the field of science and technology that intersects chemistry and electricity, so there are many applications in science and life. Oxidation – reduction reaction on electrode in electrolyte is peculiar to electrochemistry. The theory of electrolyte clarifies the law of ionic conductivity, while thermodynamics clarifies the structure of the double - layer above the interface between a solid electrode and  electrolyses as well as the thermodynamic role of the types of electrochemical potentials, especially electrode potentials, while the kinetics of the electrochemical reaction is determined by the current density and controlled by the rule of electrodic processes with the overpotential and polarization. The laws of electrochemical reactions are applied to the development of the analytical technique of qualitative and quantitative of materials as well as the characteristics of electrode reactions. Electrochemical reactions have also been the basis for the formation of electrochemical components on the basis of the laws of ion transport and the scope of control of processes by electrochemical sensing. The advantage of using electrochemistry to transform into energy chemistry has been exploited in the technologies of manufacturing all nonferrour metals, inorganic, organic chemicals, and pharmaceuticals. Metal material processing methods as well as protection, the addition of functions to metal surfaces as well as anti-corrosion of metals by electrochemical technology also create special effects. The electrochemical power source for the production and storage of electrical energy is also of great importance and value as the basis for the modern development and intelligentization of all sectors of society. Electrochemistry also contributes to rapid and effective access to current areas such as environmentally effective control and treatment, diagnosis, and treatment in biomedical as well as the manufacturing and extraction of nanomaterials and nanotechnologies.

References

[27]. Pletcher D., Walsh F. C., Industrial Electrochemistry, Blackie academic & professional, London-New York-Tokyo, (1993).

[28]. Heinz, F., Erzeugung von NE-Metallen, VEB Deutscher Verlag für Grundstoffindustrie, Leipzig, (1978).

[29]. Habashi F., A Short history of Hydrometallurgy, Hydrometallurgy, 79 (2005), pp. 15-22.

[30]. Haupin W. E., Frank W. B., Electrometallurgy of Aluminum, Compr. Treatise Electrochem., 2 (1981), pp. 301-325.

[31]. Moorhouse J., Modern Chlor-Alkali Technology, Society of Chemical Industry, SCI, Blackwell Science, Vol. 8, (2001).

[32]. Trần Thị Ngọc Dung, Lê Tự Hải, Nguyễn Đức Hùng, Nano bạc, điều chế, đặc tính và ứng dụng, Nhà xuất bản Khoa học tự nhiên và công nghệ, (2019) (in Vietnamese).

[33]. Mai Thanh Tùng, Trương Ngọc Liên, Hoàng Thị Bích Thủy, Kỹ thuật điện phân, Nhà xuất bản Bách khoa Hà Nội, (2016) (in Vietnamese).

[34]. F. Hine, B.V. Tilak, Viswanathan, Chemistry and chemical engineering in the chlor –alkali industrie, in R.E. White, J. O’M. Bockris, B. E. Conway, Modern aspects of chemistry, No. 18, Plenum Press, New York and London, (1986).

[35]. Lund, H., Hammerich, O., Organic Electrochemistry, Marcel Dekker, INC.2001.

[36]. Volke J., Liska F., Electrochemistry in organic synthesis, Springer Verlag, 1994.

[37]. James Grimshaw, Electrochemical reactions and mechanisms in organic chemistry, Elsevier, 2000.

[38]. Nguyễn Văn Sưa, Nguyễn Văn Ngũ, Hoàn thiện bề mặt sản phẩm thép không gỉ bằng phương pháp đánh bóng điện hóa, Tạp chí Khoa học và Công nghệ, 2008, 48(4), 93-96 (in Vietnamese).

[39]. Adam Ruszaj, Józef Gawlik, Sebastian Skoczypiec, Electrochemical machining – special equipment and applications in aircraft industry, Management and Production Engineering Review, 2016, 7(2), 34–41.

[40]. Nasser Kanani, Electroplating, Basic principles, Processes and Practice, Atotech Deutschland GmbH, Berlin, Germany, 2006.

[41]. Mai Thanh Tùng, Kỹ thuật mạ lên nền nhựa, Nhà xuất bản Bách khoa, Hà Nội, 2008 (in Vietnamese)

[42]. Nguyễn Đức Hùng, Kỹ Thuật mạ điện, Nhà xuất bản KH&KT HN, Hà Nội, 1989, Nhà xuất bản Thanh niên, TB 2001.

[43]. Nestor Perez, Electrochemistry and corrosion science, Kluwer Academic Publishers, New York, Boston, Dordrecht, London, Moscow, 2004.

[44]. Philip A. Schweitzer, Fundamental of metallic corrosion: atmospheric and media corrosion of metals, CRC Press, 2007.

[45]. Trương Ngọc Liên, Ăn mòn và bảo vệ kim loại, Nhà xuất bản KH& KT, 2004 (in Vietnamese).

[46]. Nguyễn Đức Hùng, Sổ tay mạ, nhúng, phun, Nhà xuất bản KH&KT, Hà Nội, 2001 (in Vietnamese)

[47]. A. Strauch, Lehrbuch für Galvaniseure, VEB Deutscher Verlag fuer Grundstoffindustrie, Leipzig, 1976.

[48]. Nguyễn Đức Hùng, Nguyễn Duy Kết - Công nghệ mạ điện hóa không bể mạ, Tạp chí

Khoa học và Công nghệ, 2006, 44(2) 70-75 (in Vietnamese).

[49]. Nguyễn Khương, Những quy trình kĩ thuật mạ kim loại và hợp kim, NXB Khoa học và

Kỹ thuật, 1997 (in Vietnamese).

[50]. Trần Minh Hoàng, Phương pháp thiết kế xưởng mạ điện, NXB Khoa học và Kỹ thuật,

Hà Nội, 2001 (in Vietnamese).

[51]. Watanabe, T., Nano-Plating, Microstructure control theory of plated film and data base of plated film microstructure, Elsevier, 2004.

[52]. Mai Van Phuoc, Nguyen Duc Hung, Electrochemical characteristic of the sulfate solution in the formation of the Ni-CeO2-CuO composite plating, Vietnamese Journal of chemistry, 2018, 56 (4e), 258 -263.

[53]. Nguyen Duc Hung, Tran Thi Van Nga, Mai Van Phuoc, Thickness determination and control of functional Ni-composite eletrodeposited coatings, Journal of Science and Technology, 2017, 55 (1B), 1–6.

[54]. Lê Thị Phương Thảo, Nguyễn Duy Kết, Nguyễn Đức Hùng, Nghiên cứu khả năng tạo lớp mạ tổ hợp Ni-TiO2 kị nước bằng dòng xung, Tạp chí Khoa học và Công nghệ, 2013, 57(3A), 38 – 46 (in Vietnamese).

[55]. W. Machu, Elektrotauchlackierung, Verlag Chemie, 1973.

[56]. Nguyễn Đức Hùng, Nguyễn Minh Thái, Kỹ thuật xử lý không khí ẩm, Nhà xuất bản KH&KT, Hà Nội, 2007 (in Vietnamese).

[57]. S.W. Dean, G.H.D. Delgadilo, J.B. Bushman, Marine Corrosion in tropical Enviroment, USA, 2000.

[58]. Антропов,Л. И., и др, Ингибиторы коррозии металлов, Киев “Техника”, 1981.

[59]. Sedriks, A. J., Corrosion of Stainless Steels, A Wiley Interscience Publication John Wiley & Sons, Inc. 1996.

[60]. Joseph Riskin, Electrocorrosion and protection of metals, Elsevier, 2008.

[61]. Wiesener, K., Garche, J., Schneider, W.,Elektrochemische Stromquellen, Akademie - Verlag - Berlin, 1981.

[62]. Erdey-Grúz, T., Die chemischen Quellen der Energie, Akadémiai Kiadó, Budapest, 1971.

[63]. Beck, F., Euler, K.J., Elektrochemische Energiespeicher, VDE – Verlag, 1984.

[64]. Patrik Schmuki, Sannakaisa Virtanen, Electrochemistry at the Nanoscale, Springer, 2009.

[65]. David Linden, Thomas B. Reddy, Handbook of Battery, McGraw-Hill, 2002.

[66]. T.R. Crompton, Battery Reference Book, Newnes, 2000.

[67]. Vielstich, W., Brennstoffelemente, Verlag Chmie-GmbH-Weinheim/Bergstr., 1965.

[68]. Detchko Pavlov, Lead-Acid Batteries: Science and Technology, Elsevier, 2011.

[69]. Yan Shao, Electrochemical Cells – New Advances in Fundamental Researches and Applications, Published by InTech, Croatia, 2012.

[70]. Mai Thanh Tùng, Kỹ thuật nguồn điện, Nhà xuất bản Bách khoa Hà Nội, 2016 (in Vietnamese).

[71]. Ralph E. White, J. O’.M. Bockris, B. E. Conway, Modern aspects of electrochemistry, No. 18, Plenum Press, New York, 1986.

[72]. NobelPrize.org. Nobel Media AB 2021, The Nobel Prize in Chemistry 2019, <https://www.nobelprize.org/prizes/chemistry/2019/press-release/>,truy cập ngày 27 Feb 2021

Published

27-04-2022

How to Cite

Nguyễn Đức Hùng. “Electrochemistry: From Theory to Technology and Application (Part 2)”. Journal of Military Science and Technology, no. 78, Apr. 2022, pp. 3-19, doi:10.54939/1859-1043.j.mst.78.2022.3-19.

Issue

Section

Overviews