Study on fabrication and effectiveness evaluation of modified graphene and metals nanoparticles lubricating additive system
141 viewsDOI:
https://doi.org/10.54939/1859-1043.j.mst.FEE.2022.285-293Keywords:
Graphene; Nano silver; Lubricant additives.Abstract
In this paper, we report the fabrication of an anti-wear, anti-friction lubricating additive system based on modified graphene and modified Ag nanoparticles. The addition of the lubricating additive system to engine oil does not change the characteristics of the oil, but increases lubricating efficiency due to reduced friction, and leads to an increase in engine power ~5% and 12.2% with tested engine, reducing fuel consumption by ~10%, reducing CxHy pollutant emissions by ≥30% and reducing smoke by 57% depending on the working mode of the engine. The effectiveness of the synthesis and modification process of graphene and Ag nanoparticles were analyzed by FTIR, TGA, SEM, and TEM. The lubricating properties of the additive system and oil were evaluated according to the ASTM D2783 standard. The effectiveness of engine power increase, fuel consumption, and emissions reduction was evaluated by Tested on 1.25-ton diesel transport vehicles and S195 single-cylinder diesel engine.
References
[1]. A. K. Geim and K. S. Novoselov, “The rise of graphene”, Nat. Mater., 6, 183–191 (2007). DOI: https://doi.org/10.1038/nmat1849
[2]. S. Choudhary, H. P. Mungse, O. P. Khatri, “Dispersion of alkylated graphene in organic solvents and its potential for lubrication applications”, J. Mater. Chem., 22, 21032–21039 (2012). DOI: https://doi.org/10.1039/c2jm34741e
[3]. T. Filleter, J. L. McChesney, A. Bostwick, E. Rotenberg, K. V. Emtsev, T. Seyller, K. Horn, R. Bennewitz, “Friction and Dissipation in Epitaxial Graphene Films”, Phys. Rev. Lett., 102, 086102 (2009). DOI: https://doi.org/10.1103/PhysRevLett.102.086102
[4]. D. Berman, A. Erdemir, A. V. Sumant, “Reduced Wear and Friction Enabled by Graphene Layers on Sliding Steel Surfaces in Dry Nitrogen”. Carbon, 54, 454-459 (2013). DOI: https://doi.org/10.1016/j.carbon.2012.11.061
[5]. H. P. Mungse, O. P. Khatr. “Chemically Functionalized Reduced Graphene Oxide as a Novel Material for Reduction of Friction and Wear”. J. Phys. Chem. C, 118 (26), 14394–14402 (2014). DOI: https://doi.org/10.1021/jp5033614
[6]. H. D. Huang, J.P. Tu, L. P. Gan, C. Z. Li, “An investigation on tribological properties of graphite nanosheets as oil additive”, Wear, 261, 140–144, (2006). DOI: https://doi.org/10.1016/j.wear.2005.09.010
[7]. W. Zhang, M. Zhou, H. Zhu, Y. Tian, K. Wang, J. Wei, F. Ji, X. Li, Z. Li, P. Zhang, D. Wu, “Tribological properties of oleic acid-modified graphene as lubricant oil additives”, J. Phys. D: Appl. Phys. 44, 205303 (2011). DOI: https://doi.org/10.1088/0022-3727/44/20/205303
[8]. T. Chen, Y. Xia, Zh. Jia, Zh. Liu, H. Zhang, “Synthesis, Characterization, and Tribological Behavior of Oleic Acid Capped Graphene Oxide”, Journal of Nanomaterials, Article ID 654145 (2014). DOI: https://doi.org/10.1155/2014/654145
[9]. S. J. Hana, H. I. Leea, H. M. Jeonga, B. K. Kimb, A. V. Raghuc, K. R. Reddyd, “Graphene Modified Lipophilically by Stearic Acid and its Composite with Low Density Polyethylene”, J. Macromolecular Science B: Physics, 53(7), (2014). DOI: https://doi.org/10.1080/00222348.2013.879804
[10]. Nguyễn Hữu Vân, Trần Văn Hiền, Hà Quốc Bảng, Nguyễn Mạnh Tường, “Phụ gia alkyl graphen cho dầu bôi trơn”, Tạp chí hóa học, 53(e1)93-98, (2015).
[11]. Nguyễn Hữu Vân, Hà Quốc Bảng, Nguyễn Duy Anh, Nguyễn Công Thắng, Trần Văn Hiền, “Tổng hợp graphen oxit bằng phương pháp điện hóa”, Tạp chí hóa học, 58(5E12), 162-166, (2020).
