Synthesis of nanocomposites material Fe/ GNPs/ Porphyrene and the electrochemical properties investigation

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Authors

  • Nguyen Thi Xuan Quynh School of Chemical Engineering, Hanoi University of Science and Technology
  • Le Long Vu School of Chemical Engineering, Hanoi University of Science and Technology
  • Nguyen Thuy Trang School of Chemical Engineering, Hanoi University of Science and Technology
  • Khong Manh Hung Institute of Chemistry and Materials, Academy of Military Science and Technology
  • Nguyen Lan Huong School of Biotechnology and Food Technology, Hanoi University of Science and Technology
  • La Duc Duong Institute of Chemistry and Materials, Academy of Military Science and Technology
  • Dang Trung Dung (Corresponding Author) School of Chemical Engineering, Hanoi University of Science and Technology

DOI:

https://doi.org/10.54939/1859-1043.j.mst.89.2023.60-66

Keywords:

: zero valent iron; graphene; porphyrin; electrochemical properties; electrochemical sensors

Abstract

Electrochemical sensors are currently being developed and widely applied in many fields with new materials to increase the accuracy and selectivity of the method. In this study, Fe/GNPs materials were synthesized from green chemistry method, combined with recombinant TCPP process to create Fe/GNPs/TCPP nanocomposite materials. The structure and morphology of the formed products were studied by scanning electron microscopy (SEM), X-ray diffraction (XRD), Fourier transform infrared spectroscopy (FTIR), Raman spectroscopy. The morphological and structural analysis results of the products showed that Fe/GNPs/TCPP nanocomposites were formed from nano-structured zero valent iron particles with an average size of 15-60 nm uniformly distributed on the surface of graphene plates 2-10 nm thick, interspersed with porphyrin nanofibers with a diameter of 30 nm. The materials were investigated and evaluated for their electrochemical properties through cyclic potential scanning (CV), electrochemical impedance spectroscopy (EIS) on a three-electrode electrochemical system. The  electrochemical analysis results have demonstrated that Fe/GNPs/TCPP nanocomposite materials have good properties suit for application as electrochemical sensors in the analysis of residues of antibiotics, pesticides in agricultural production.

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Published

25-08-2023

How to Cite

Nguyễn, T. X. Q., L. V. Lê, T. T. Nguyễn, M. H. Khổng, L. H. Nguyễn, Đức D. Lã, and P. D. Dang Trung. “Synthesis of Nanocomposites Material Fe/ GNPs/ Porphyrene and the Electrochemical Properties Investigation”. Journal of Military Science and Technology, vol. 89, no. 89, Aug. 2023, pp. 60-66, doi:10.54939/1859-1043.j.mst.89.2023.60-66.

Issue

Vol. 89 (2023)

Section

Research Articles