Synthesis, optical and magnetic properties of spinel-structured CoAl2O4 nanomaterials

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Authors

  • Nguyen Thi Hien Thai Nguyen University of Science
  • Nguyen Xuan Ca Thai Nguyen University of Science
  • Nguyen Thi Luyen Thai Nguyen University of Science
  • Nguyen Trung Kien Thai Nguyen University of Science
  • Nguyen Thi Khanh Van Thai Nguyen University of Science
  • Ngo Thi Lan Thai Nguyen University of Science
  • Pham Minh Tan (Corresponding Author) Thai Nguyen University of Technology

DOI:

https://doi.org/10.54939/1859-1043.j.mst.89.2023.110-116

Keywords:

Spinel; Optical properties; Magnetic properties; CoAl2O4; Color printing.

Abstract

Spinel-structured CoAl2O4 nanocrystals (NCs) with sizes from 54-60 nm have been successfully fabricated by the sol-gel method combined with a solid-phase reaction. The effect of sample annealing temperature on optical and magnetic properties, structure, and size was investigated. The spinel structure and size of the CoAl2O4 NCs were confirmed and calculated through X-ray diffraction (XRD). The vibrational characteristics and binding groups of the CoAl2O4 NCs were investigated by infrared absorption spectroscopy and Raman scattering. The absorption and luminescence properties of the CoAl2O4 NCs were investigated through absorption spectroscopy and fluorescence measurements. Hysteresis curve measurement was used to determine the magnetic nature of the material. This study provides new information on optical and magnetic properties and application prospects of CoAl2O4 nanomaterials in the field of digital color printing.

References

[1]. T. Wu, S. Sun, J. Song, et al, “Iron-facilitated dynamic active-site generation on spinel CoAl2O4 with self-termination of surface reconstruction for water oxidation”, Nat. Catal, Vol. 2, pp. 763–772, (2019). DOI: https://doi.org/10.1038/s41929-019-0325-4

[2]. S. Khademolhoseini, R. Talebi, “Green synthesis and characterization of cobalt aluminate nanoparticles and its photocatalyst application”, J. Mater. Sci. Mater. El, Vol. 27, pp. 2938–2943, (2016). DOI: https://doi.org/10.1007/s10854-015-4113-x

[3]. T. Gholami, M. Salavati-Niasari, S. Varshoy, “Investigation of the electrochemical hydrogen storage and photocatalytic properties of CoAl2O4 pigment: Green synthesis and characterization”, Int. J. Hydrogen Energy, Vol. 41, pp. 9418–9426, (2016). DOI: https://doi.org/10.1016/j.ijhydene.2016.03.144

[4]. J. Li, M.J. Xu, G. Yao, B. Lai, “Enhancement of the degradation of atrazine through CoFe2O4 activated peroxymonosulfate (PMS) process: kinetic, degradation intermediates, and toxicity evaluation”, Chem. Eng. J, Vol. 348, pp. 1012–1024, (2018). DOI: https://doi.org/10.1016/j.cej.2018.05.032

[5]. X. Duan, M. Pan, F. Yu, D. Yuan, “Synthesis, structure and optical properties of CoAl2O4 spinel nanocrystals”, Journal of Alloys and Compounds, Vol. 509, pp. 1079–1083, (2011). DOI: https://doi.org/10.1016/j.jallcom.2010.09.199

[6]. D. L. Wei, Z. L. Jia, K. G. Jing, “Synthesis and characterization of nanocrystalline CoAl2O4 spinel powder by low temperature combustion”, J. Eur. Ceram. Soc, Vol. 23, pp. 2289, (2003). DOI: https://doi.org/10.1016/S0955-2219(03)00081-5

[7]. Y. Zhao, H. Z. An, J. Feng, Y. M. Ren, J. Ma, “Impact of Crystal Types of AgFeO2 Nanoparticles on the Peroxymonosulfate Activation in the Water”, Environ. Sci. Technol, Vol. 53, pp. 4500–4510, (2019). DOI: https://doi.org/10.1021/acs.est.9b00658

[8]. T. Yu, Z X Shen, Y. Shi, J Ding, “Cation migration and magnetic ordering in spinel CoFe2O4 powder: micro-Raman scattering study”, J. Phys. Condense Matter, Vol. 14, pp. 613, (2002). DOI: https://doi.org/10.1088/0953-8984/14/37/101

[9]. L. Torkian, M. Daghighi, “Effects of β-alanine on morphology and optical properties of CoAl2O4 nanopowders as a blue pigment”, Adv. Powder technol, Vol. 25, pp. 739-744, (2014). DOI: https://doi.org/10.1016/j.apt.2013.11.003

[10]. A. Irshad, M. Shahid, S. M. El-Bahy, I. H. El-Azab, G. A.M. Mersal, M. M. Ibrahim, P. O. Agboola, I. Shakir , “Nickel doped CoAl2O4@CNT nanocomposite: Synthesis, characterization, and evaluation of sunlight driven catalytic studies”, Phys. B: Condensed Matter, Vol. 636 , pp. 413873, (2022). DOI: https://doi.org/10.1016/j.physb.2022.413873

[11]. I. T. Ho, K. C. Chang, D. Tiparti, A. C. Yeh, S. Tin, “Toward the Understanding of CoAl2O4 Additions on the Formation of Microstructure in Alloy 718 Processed by Laser Powder Bed Fusion”, Metallurgical and Materials Transactions A, Vol. 54, pp. 23–38, (2023). DOI: https://doi.org/10.1007/s11661-022-06876-y

[12]. S. Cava, S. M. Tebcherani, S. A. Pianaro, C. A. Paskocimas, E. Longo, J. A.Varela, “Structural and spectroscopic analysis of γ-Al2O3 to α-Al2O3-CoAl2O4 phase transition”, Mater. Chem. Phys, Vol. 97, pp. 102-108, (2006). DOI: https://doi.org/10.1016/j.matchemphys.2005.07.057

[13]. D. Rangappa, S. Ohara, T. Naka, A. Kondo, M. Ishii, T. Adschiri, “Synthesis and organic modification of CoAl2O4 nanocrystals under supercritical water conditions”, Journal of Materials Chemistry, Vol. 17, pp. 4426–4429, (2007). DOI: https://doi.org/10.1039/b705760a

[14]. M. S. Niasari, M. F. Khouzani, F. Davar, “Bright blue pigment CoAl2O4 nanocrystals prepared by modified sol–gel method”, J. sol-gel Sci. technol, Vol. 52, pp. 321-327, (2009). DOI: https://doi.org/10.1007/s10971-009-2050-y

[15]. L. Fei, W. Zhang, L. He, X. Bai, Y. Song , Y. Zhao. “3D porous flower-like CoAl2O4 to boost the photocatalytic CO2 reduction reaction”, J. Mater. Chem. A, Vol. 11, pp. 2826-2835, (2023). DOI: https://doi.org/10.1039/D2TA08947E

[16]. N. Srisawad, W. Chaitree, O. Mekasuwandumrong, P. Praserthdam, J. Panpranot, “Formation of CoAl2O4 nanoparticles via low-temperature solid-state reaction of fine gibbsite and cobalt precursor”, Journal of Nanomaterials, Vol. 2012, 108369, 8 pages, (2012). DOI: https://doi.org/10.1155/2012/108369

[17]. M. Zayat, D. Levy, “Blue CoAl2O4 Particles Prepared by the Sol−Gel and Citrate−Gel Methods”, Chemistry of Materials, Vol. 12, pp. 2763–2769, (2000). DOI: https://doi.org/10.1021/cm001061z

[18]. R. Chueachot, R. Nakhowong, “Synthesis and optical properties of blue pigment CoAl2O4 nanofibers by electrospinning”, Materials Letters, Vol. 259, pp. 126904, (2020). DOI: https://doi.org/10.1016/j.matlet.2019.126904

[19]. S. Guo, H. Tang, L. You, H. Zhang, J. Li, K. Zhou, “Combustion synthesis of mesoporous CoAl2O4 for peroxymonosulfate activation to degrade organic pollutants”, Chinese Chemical Letters, Vol. 32 , pp. 2828-2832, (2021). DOI: https://doi.org/10.1016/j.cclet.2021.01.019

[20]. K. S. Ahn, Y. Yan, M. S. Kang, J. Y. Kim, S. Shet, “CoAl2O4–Fe2O3CoAl2O4–Fe2O3 p-n-nanocomposite electrodes for photoelectrochemical cells”, Appl. Phys. Lett, Vol. 95, pp. 022116, (2009).

[21]. L. Weizhong, Q. Qiu, F. Wang, S. Wei, B. Liu, Z. Luo, “Sonochemical synthesis of cobalt aluminate nanoparticles under various preparation parameters”, Ultrasonics Sonochemistry, Vol. 17, pp. 793–801, (2010). DOI: https://doi.org/10.1016/j.ultsonch.2010.01.018

[22]. G. Y. Lee, K. H. Ryu, H. G. Kim, Y. Y. Kim, “The Preparation of Blue CoAl2O4 Powders by the Malonate Method: The Effect of the Amount of Malonic Acid Used, the Formation Pathway of CoAl2O4 Crystallites”, Bull. Korean Chem. Soc, Vol. 30, pp. 373, (2009). DOI: https://doi.org/10.5012/bkcs.2009.30.2.373

[23]. K. Agilandeswari, A. R. Kumar, “Synthesis, Characterisation, Synthesis, characterisation, optical and luminescence properties of CoAl2O4”, Solid State Physics AIP Conf. Proc 1665, 120022, (2015). DOI: https://doi.org/10.1063/1.4918129

[24]. J. Chandradassa, M. Balasubramanianb, K. H. Kim, “Size effect on the magnetic property of CoAl2O4 nanopowders prepared by reverse micelle processing”, Journal of Alloys and Compounds, Vol. 506, pp. 395–399, (2010). DOI: https://doi.org/10.1016/j.jallcom.2010.07.014

[25]. S. Sun, H. Zheng, D. B. Robinson, S. Raoux, P. M. Rice, S. X. Wang, G. Li, “Monodisperse MFe2O4 (M = Fe, Co, Mn) Nanoparticles”, J. Am. Chem. Soc, Vol. 126, pp. 273–279, (2004). DOI: https://doi.org/10.1021/ja0380852

[26]. D. Yu, X. Sun, J. Zou, Z. Wang, F. Wang, K. Tang, “Oriented Assembly of Fe3O4 Nanoparticles into Monodisperse Hollow Single-Crystal Microspheres”, J. Phys. Chem. B, Vol. 110, pp. 21667–21671, (2006). DOI: https://doi.org/10.1021/jp0646933

[27]. R. H. Kodama, “Magnetic nanoparticles”, J. Magn. Magn. Mater, Vol. 200, pp. 359–372, (1999). DOI: https://doi.org/10.1016/S0304-8853(99)00347-9

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Published

25-08-2023

How to Cite

Nguyễn Thị, H., C. Nguyễn Xuân, L. Nguyễn Thị, Nguyễn Trung Kiên, V. Nguyễn Thị Khánh, L. Ngô Thị, and M. T. Phạm. “Synthesis, Optical and Magnetic Properties of Spinel-Structured CoAl2O4 Nanomaterials”. Journal of Military Science and Technology, vol. 89, no. 89, Aug. 2023, pp. 110-6, doi:10.54939/1859-1043.j.mst.89.2023.110-116.

Issue

Vol. 89 (2023)

Section

Research Articles

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