Study on the effect of efficiency recovery ammonium and phosphate in rubber wastewater by struvite precipitation
206 viewsDOI:
https://doi.org/10.54939/1859-1043.j.mst.85.2023.82-87Keywords:
Ammonium recovery; Struvite precipitation; Rubber wastewater.Abstract
The removal and recovery of Ammonium and phosphorus from rubber wastewater is an important issue to reduce water and environmental pollution. The aim of this study was to recover N and P from rubber wastewater through a crystallization process at different operational conditions. The effects of pH, Mg/P/NH4 molar ratio, and reaction time on the yield of struvite recovery were discussed. The results showed that at the pH value of 9.5, The reaction time is 60 minutes, the optimal mole ratio Mg2+: P-PO43-: N-NH4 is 1.3: 1: 1, the efficiency of ammonium and phosphorus removal is 82 and 96%, respectively; The volume of struvite precipitate obtained is 4.16 g/liter of rubber wastewater.
References
[1]. Lê Văn Cát, “Xử lý nước thải giàu hợp chất nitơ và phốt pho,” Nhà xuất bản Khoa học Tự nhiên và Công nghệ Hà Nội, (2007).
[2]. Viện Nghiên cứu Cao su Việt Nam (RRIV), Đại học Bách khoa Hà Nội (HUST) và Đại học Công nghệ Nagaoka (NUT), “Báo cáo tổng kết Dự án tạo lập chu trình vòng khí thải cacbon với cao su thiên nhiên (ESCANBER),” Hà Nội, (2016).
[3]. Li B., Boiarkina I., Yu W., Huang H. M., Munir T., et al, “Phosphorous recovery through struvite crystallization: Challenges for future design,” Sci. Total Environ., Vol. 648, pp. 1244–1256, (2019). DOI: https://doi.org/10.1016/j.scitotenv.2018.07.166
[4]. Siciliano A., Limonti C., Curcio G. M., Molinari R, “Advances in Struvite Precipitation Technologies for Nutrients Removal and Recovery from Aqueous Waste and Wastewater,” Sustainability, Vol. 12, No. 18, pp. 7538, (2020).
[5]. Siciliano A., Limonti C., Curcio G. M., Molinari R, “Advances in Struvite Precipitation Technologies for Nutrients Removal and Recovery from Aqueous Waste and Wastewater,” Sustainability, Vol. 12, No. 18, pp. 7538, (2020). DOI: https://doi.org/10.3390/su12187538
[6]. Van der Hoek J., Duijff R., Reinstra O, “Nitrogen Recovery from Wastewater: Possibilities, Competition with Other Resources, and Adaptation Pathways,” Sustainability, Vol. 10, No. 12, pp. 4605, (2018). DOI: https://doi.org/10.3390/su10124605
[7]. Booker, N. A., Priestley, A. J., & Fraser, I. H, “Struvite formation in wastewater treatment plants: Opportunities for nutrient recovery,” Environmental Technology, Vol. 20. No. 7, pp. 777-782, (2010). DOI: https://doi.org/10.1080/09593332008616874
[8]. Tansel B., Lunn G., Monje O, “Struvite formation and decomposition characteristics for ammonia and phosphorus recovery: A review of magnesium-ammonia-phosphate interactions,” Chemosphere, Vol. 194, pp. 504–514, (2018). DOI: https://doi.org/10.1016/j.chemosphere.2017.12.004
[9]. Najib M. D. authorShaymaa M. A. A. K. Z. M, “Struvite Crystallization: An Effective Technology for Nitrogen Recovery in Landfill Leachate,” Water Sci. Technol. Libr., Vol. 92, pp. 143–166, (2020). DOI: https://doi.org/10.1007/978-3-030-42641-5_9
[10]. Xiaoning Liu, Zhengyi Hu, Chunyou Zhu, Guoqi Wen, Xianchao Meng, Jia Lu, “Influence of process parameters on phosphorus recovery by struvite formation from urine” Water Sci. Technol, Vol. 68, No. 11, pp. 2434-2340, (2013). DOI: https://doi.org/10.2166/wst.2013.514